Diagram of the dually charged membrane fabricated via catechol-amine
chemistry surface engineering. Credit: CAO Yang.
A research group led by Prof. Wan Yinhua from the Institute of Process Engineering (IPE) of the Chinese Academy of Sciences has developed a robust, dually charged loose nanofiltration (NF) membrane for highly efficient dye/salt separation.
NF is an effective method for treating textile wastewater. However, most commercially available NF membranes exhibit low selectivity in dye/salt separation due to their negatively charged, dense separation layer.
The researchers prepared an NF membrane with a loose and dually charged separation layer based on a simple catechol-amine chemistry surface engineering strategy.
In the strategy, polyethyleneimine (PEI) was coated on a hydrolyzed polyacrylonitrile substrate to construct a positively charged intermediate layer, followed by co-deposition of tannic acid (TA) and poly-γ-glutamic acid (γ-PGA) to engineer a negatively charged top layer.
The loose separation layer structure was attributed to the competitive reaction induced by polyphenols, which means the covalent interactions, hydrogen bonding and electrostatic adsorption among TA, γ-PGA and PEI hindered the rapid and non-uniform self-polymerization of TA.
The pre-reaction between TA and γ-PGA could further weaken those competitive reactions, tuning the pore size and charging property, and thus improving the separation performance.
Due to the synergy between size exclusion and electrostatic interaction of the loose dual-charged separation layer, the prepared membrane exhibited outstanding water permeability (36.9 Lm-2h-1bar-1) with low salt rejections (11.1% for Na2SO4) and high rejection to both positively and negatively charged dyes.
Moreover, this dually charged membrane also showed excellent acid resistance as well as satisfactory antifouling performance and long-term stability.
“This work provides a novel dimension toward the environmentally friendly approach for preparing highly selective separation membranes, and this versatile coating strategy can be employed to fabricate/modify the membranes with controllable properties for various separation applications,” said Prof. Luo Jianquan from IPE.
The study was published in the Journal of Membrane Science on March 21.
